By studying the heat semigroup, we prove Li-Yau type estimates for bounded and positive solutions of the heat equation on graphs, under the assumption of the curvature-dimension inequality $CDE'(n,0)$, which can be consider as a notion of curvature for graphs. Furthermore, we derive that if a graph has non-negative curvature then it has the volume doubling property, from this we can prove the Gaussian estimate for heat kernel, and then Poincar\'{e} inequality and Harnack inequality. As a consequence, we obtain that the dimension of space of harmonic functions on graphs with polynomial growth is finite, which original is a conjecture of Yau on Riemannian manifold proved by Colding and Minicozzi. Under the assumption of positive curvature on graphs, we derive the Bonnet-Myers type theorem that the diameter of graphs is finite and bounded above in terms of the positive curvature by proving some Log Sobolev inequalities.

Let $K_k$, $C_k$, $T_k$, and $P_{k}$ denote a complete graph on $k$ vertices, a cycle on $k$ vertices, a tree on $k+1$ vertices, and a path on $k+1$ vertices, respectively. Let $K_{m}-H$ be the graph obtained from $K_{m}$ by removing the edges set $E(H)$ of the graph $H$ ($H$ is a subgraph of $K_{m}$). A sequence $S$ is potentially $K_{m}-H$-graphical if it has a realization containing a $K_{m}-H$ as a subgraph. Let $\sigma(K_{m}-H, n)$ denote the smallest degree sum such that every $n$-term graphical sequence $S$ with $\sigma(S)\geq \sigma(K_{m}-H, n)$ is potentially $K_{m}-H$-graphical. In this paper, we determine the values of $\sigma (K_{r+1}-H, n)$ for $n\geq 4r+10, r\geq 3, r+1 \geq k \geq 4$ where $H$ is a graph on $k$ vertices which contains a tree on $4$ vertices but not contains a cycle on $3$ vertices. We also determine the values of $\sigma (K_{r+1}-P_2, n)$ for $n\geq 4r+8, r\geq 3$.

We explore the tunneling behavior of a quantum particle on a finite graph in the presence of an asymptotically large potential with two or three potential wells. The behavior of the particle is primarily governed by the local spectral symmetry of the graph around the wells. In the case of two wells the behavior is stable in the sense that it can be predicted from a sufficiently large neighborhood of the wells. However in the case of three wells we are able to exhibit examples where the tunneling behavior can be changed significantly by perturbing the graph arbitrarily far from the wells.

We prove an explicit formula of ChungYaus Discrete Greens functions as well as hitting times of random walks on graphs. The formula is expressed in terms of two natural counting invariants of graphs. Uniform derivations of Greens functions and hitting times for trees and other special graphs are given.

We modify the definition of Ricci curvature of Ollivier of Markov chains on graphs to study the properties of the Ricci curvature of general graphs, Cartesian product of graphs, random graphs, and some special class of graphs.