The zero dissipation limit of the compressible heat-conducting NavierStokes equations in the presence of the shock is investigated. It is shown that when the heat conduction coefficient and the viscosity coefficient satisfy = O (), = O (), c> 0, as 0 (see (1.3)), if the solution of the corresponding Euler equations is piecewise smooth with shock wave satisfying the Lax entropy condition, then there exists a smooth solution to the NavierStokes equations, which converges to the piecewise smooth shock solution of the Euler equations away from the shock discontinuity at a rate of . The proof is given by a combination of the energy estimates and the matched asymptotic analysis introduced in [3].