The diffusive transport of passive tracers or particles can be enhanced by incompressible, turbulent flow fields. Analyzing the effective behavior is a challenging problem with theoretical and practical importance in many areas of science and engineering, ranging from the transport of mass, heat, and pollutants in geophysical flows to sea ice dynamics and turbulent combustion. The long time, large scale behavior of such systems is equivalent to an enhanced diffusion process with an effective diffusivity tensor D*. Two different formulations of integral representations for D* were developed for the case of time-independent fluid velocity fields, involving spectral measures of bounded self-adjoint operators acting on vector fields and scalar fields, respectively. Here, we extend both of these approaches to the case of space-time periodic velocity fields, allowing for chaotic dynamics, providing rigorous integral representations for D* involving spectral measures of unbounded self-adjoint operators.We prove the different formulations are equivalent. Their correspondence follows from a one-to-one isometry between the underlying Hilbert spaces. We also develop a Fourier method for computing D*, which captures the phenomenon of residual diffusion related to Lagrangian chaos of a model flow. This is reflected in the spectral measure by a concentration of mass near the spectral origin.

For autonomous Tonelli systems on $\R^n$, we develop an intrinsic proof of the existence of generalized characteristics using sup-convolutions. This approach, together with convexity estimates for the fundamental solution, leads to new results such as the global propagation of singularities along generalized characteristics.

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For the free surface problem of the highly subsonic heat-conducting inviscid flow in 2-D and 3-D, a priori estimates for geometric quantities of free surfaces, such as the second fundamental form and the injectivity radius of the normal exponential map, and the Sobolev norms of fluid variables are proved by investigating the coupling of the boundary geometry and the interior solutions. An interesting feature for the free surface problem studied in this paper is the loss of one more derivative than the problem of incompressible Euler equations for which a geometric approach was introduced by Christodoulou and Lindblad in [11]. Due to the loss of one more derivative and loss of symmetry of equations, the geometric approach in [11] needs to be substantially developed by exploring the interaction of large variation of temperature, heat-conduction, non-zero divergence of the fluid velocity and the evolution of free surfaces.

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