The spectral radius of a graph is the largest eigenvalue of the adjacency matrix of the graph. Let T(n,D
l) be the tree which minimizes the spectral radius of all trees of order n with exactly l vertices of maximum degree D
. In this paper, T(n,D
l) is determined for D=3, and for l<= 3 and n large enough. It is proven that for sufficiently large n, T(n, 3, l) is a caterpillar with (almost) uniformly distributed legs, T(n,D
2) is a dumbbell, and T(n,
D,3) is a tree consisting of three distinct stars of order D
connected by three disjoint paths of (almost) equal length from their centers to a common vertex. The unique tree with the largest spectral radius among all such trees is also determined. These extend earlier results of Lov´asz and Pelik´an, Simi´c and To˘si´c, Wu, Yuan and Xiao, and Xu, Lin and Shu.

We introduce the notion of Bonnet-Myers and Lichnerowicz sharpness in the Ollivier Ricci curvature sense. Our main result is a classification of all self-centered Bonnet-Myers sharp graphs (hypercubes, cocktail party graphs, even-dimensional demi-cubes, Johnson graphs , the Gosset graph J(2n, n) and suitable Cartesian products). We also present a purely combinatorial reformulation of this result. We show that Bonnet-Myers sharpness implies Lichnerowicz sharpness and classify all distance-regular Lichnerowicz sharp graphs under the additional condition θ_1=b_1-1. We also relate Bonnet-Myers sharpness to an upper bound of Bakry-Émery ∞-curvature, which motivates a general conjecture about Bakry-Émery ∞-curvature.

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We study the cluster algebras arising from cluster tubes with rank bigger than 1. Cluster tubes are 2−Calabi-Yau triangulated categories which contain no cluster tilting objects, but maximal rigid objects. Fix a certain maximal rigid object T in the cluster tube C_n of rank n. For any indecomposable rigid object M in C_n, we define an analogous X_M of Caldero-Chapton's formula (or Palu's cluster character formula) by using the geometric information of M. We show that X_M,X_{M′} satisfy the mutation formula when M,M′ form an exchange pair, and that X_? : M↦X_M gives a bijection from the set of indecomposable rigid objects in C_n to the set of cluster variables of cluster algebra of type C_{n−1}, which induces a bijection between the set of basic maximal rigid objects in C_n and the set of clusters. This strengths a surprising result proved recently by Buan-Marsh-Vatne that the combinatorics of maximal rigid objects in the cluster tube Cn encode the combinatorics of the cluster algebra of type B_{n−1} since the combinatorics of cluster algebras of type B_{n−1} or of type C_{n−1} are the same by a result of Fomin and Zelevinsky. As a consequence, we give a categorification of cluster algebras of type C.