The concept of matrix canonical realization of a Lie algebra is introduced. The generators of the Lie algebra of the pseudoorthogonal group n) are recurrently expressed in terms of matrices with polyno-mial elements in a certain number of quantum-mechanical canonical variables p~, qi and they depend on a certain number of free real para-meters. The realizations are, in the well-defined sense, skew-hermitean and Casimir operators are multiples of the identity element. Part of them are usual canonical realizations.