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In this paper, we propose a rigorous and accurate non-local (in the oversampled region) upscaling framework based on some recently developed multiscale methods [10]. Our proposed method consists of identifying multi-continua parameters via local basis functions and constructing non-local (in the oversampled region) transfer and effective properties. To achieve this, we significantly modify our recent work proposed within Generalized Multiscale Finite Element Method (GMsFEM) in [10] and derive appropriate local problems in oversampled regions once we identify important modes representing each continuum. We use piecewise constant functions in each fracture network and in the matrix to write an upscaled equation. Thus, the resulting upscaled equation is of minimal size and the unknowns are average pressures in the fractures and the matrix. Note that the use of non-local upscaled model for porous

Differential optical absorption spectroscopy (DOAS) is a powerful tool for detecting and quantifying trace gases in atmospheric chemistry\cite {Platt_Stutz08}. DOAS spectra consist of a linear combination of complex multi-peak multi-scale structures. Most DOAS analysis routines in use today are based on least squares techniques, for example, the approach developed in the 1970s uses polynomial fits to remove a slowly varying background, and known reference spectra to retrieve the identity and concentrations of reference gases. An open problem is to identify unknown gases in the fitting residuals for complex atmospheric mixtures.

We introduce the notions of a path complex and its homologies. Particular cases of path homologies are simplicial homologies and digraph homologies. We state and prove some properties of path homologies, in particular, the K¨unneth formulas for Cartesian product and join, which happen to be true at the level of chain complexes.