We show that the angles between Teichmüller geodesic rays issuing from a common point, defined by using the law of cosines, do not always exist. The proof uses an estimation for the Teichmüller distance on finite dimensional Teichmüller spaces. As a consequence, the Teichmüller space equipped with the Teichmüller metric is not a CAT(k) space for any k∈R . We also discuss some necessary conditions for the existence of angle between the Teichmüller geodesics.