This article provides a complete description of the differential Gerstenhaber algebras of all nilpotent complex structures on any real six-dimensional nilpotent algebra. As an application, we classify all pseudo-Khlerian complex structures on six-dimensional nilpotent algebras whose differential Gerstenhaber algebra is quasi-isomorphic to that of the symplectic structure. In a weak sense of mirror symmetry, this gives a classication of pseudo-Khler structures on six-dimensional nilpotent algebras whose mirror images are themselves.